Block Copolymerization of Methacrylates Using Ph2PCl/Epoxide as Preinitiator

Thiol-Ene-Methacrylates as Dental Restorative Materials

Thiol-ene systems demonstrate numerous advantageous polymerization properties in regards to rapid curing, high conversion, minimal oxygen inhibition, and reduced shrinkage stress. However, one of the drawbacks of thiol-ene systems is that commercially available monomers are not able to achieve the mechanical properties required for use as dental restorative materials. Methacrylate systems on th...

Copolymerization Using Lipase Catalyst

Enzymatic ring-opening copolymerization of lactones was carried out by using Pseudomonas f luorescens lipase in bulk. In the copolymerizaton of r-caprolactone (E-CL) and b-valerolactone at 60°C for 10 days a copolymer with molecular weight of 3.7 x 103 was obtained and its structure was found to be of random structure having both units from 13C NMR anlaysis. Effects of the feed ratio, the react...

Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods

Supercritical Carbon Dioxide Copolymerization of D,l-lactide and Glycolide Using Zinc Octoate as Catalyst

The objective of the study is the development of a new technique based on supercritical technology for the production of bioabsorbable polymeric microparticles containing pharmaceutical principles, for their use in the controlled release of medicines. For this purpose, the ring-opening copolymerization of D,L-lactide and glycolide in supercritical carbon dioxide, using zinc(II) 2-ethylhexanoate...

assessment of the efficiency of s.p.g.c refineries using network dea

data envelopment analysis (dea) is a powerful tool for measuring relative efficiency of organizational units referred to as decision making units (dmus). in most cases dmus have network structures with internal linking activities. traditional dea models, however, consider dmus as black boxes with no regard to their linking activities and therefore do not provide decision makers with the reasons...